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　　In water -based electrolytes, the differences in their oxidation and reduction potential are very large. Their combination will build a rough structured water that can be recharged by rechargeable battery system. The metal is used as anode and lithium manganate as cathode, and its CV curve scanning speed is 0.1 mv/s, and there are two pairs of oxidized reduction peaks, which are located at 4.14/3.80 and 4.28/3.93 V. From the above figure, the oxidation and reduction reaction is shown below: During the charging process, there is only one reaction in the anode. LI +ions from water -based electrolyte transportation through the overwriter, reducing the surface and sedimentary li metal on the lithium metal surface. Two reactions are performed on the cathode: li +cation is embedded in the site of the tetraonal 8A and the octopus 16C, which subsequently causes two pairs of oxidation and reduction peaks, similar to the behavior of the organic electrolyte. In the process of discharge, the reverse process occurs. Therefore, there are two pairs of oxidation and restoration peaks in our ARLB CV curve. This shows that the lithium metal of the battery chemical coating above, 0.5mol.l-1 li2so4/limn2O4 can be higher than 3.8 V in the water-based electrolytic fluid, which is far higher than the theoretical decomposition voltage of water, that is, that is, the theoretical decomposition voltage, that is, 1.229 V.

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